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CHEM-C 634: TRANSITION METAL CHEMISTRY (3 credits)

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Survey of the properties of the transition metals with emphasis on common oxidation levels, coordination geometries and compounds with "classical" ligands; "hard" and "soft" acids and bases; d-orbitals and their energies in different geometries; formation constants and the Chelate Effect, the Jahn-Teller theorem; low-, intermediate-, and high-spin systems; mixed valency; metal-ligand multiple bonding; metal-metal bonds; coordination clusters and their biological relevance.

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